𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Hydrogen peroxide oxidation catalyzed by heteropoly acids combined with cetylpyridinium chloride. Epoxidation of olefins and allylic alcohols, ketonization of alcohols and diols, and oxidative cleavage of 1,2-diols and olefins

✍ Scribed by Ishii, Yasutaka; Yamawaki, Kazumasa; Ura, Toshikazu; Yamada, Hiroshi; Yoshida, Tsutomu; Ogawa, Masaya


Book ID
118233913
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
906 KB
Volume
53
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Mntrimethyltriazacyclononane/ascorbic a
✍ Albrecht Berkessel; Christoph A. Sklorz 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 253 KB

The system comprised of manganese(II) acetate or sulfate, 1,4,7-trimethyl-1,4,7-triazacyclononane (TMTACN) and ascorbic acid efficiently catalyzes the epoxidation of olefins and the oxidation of alcohols with hydrogen peroxide. For example, in the presence of as little as 0.03 mol% of Mn 2÷, methyl