Hydrogen on rhodium (110); the formation of a high-density chemisorbed phase
β Scribed by K. Christmann; M. Ehsasi; W. Hirschwald; J.H. Block
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 501 KB
- Volume
- 131
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
TheadsorptionofH(D)onRh(110)at80Kleadstoasequenceoflatticegasphases:plx3at~=f,plx2at~=f,1x3-2H at 0 = f and 1 x 2-3H at & 3; and also the formation of a 1 x I-2H phase at .9 = 2, the first time that a chemisorbed H layer with a density nearly 2 x IO" atoms/cm' is reported for a fee surface. LEED investigations suggest the absence of surface reconstruction due to adsorbed hydrogen.
π SIMILAR VOLUMES
The steady-state polarization curve of the hydrogen evolution at highly active Pt-electrodes was determined in 5 M and 0.5 M HjSO 4 up to high current densities. The polarization curve in 5 M HzSO 4 is characterized by four regions, which differ from one another by the slope (b) of the E-log(/) curv