The flash photolysis of di-p-oxo his(oxo-molybdenum(V)) complexes in aqueous solutions of perchloric acid in the presence of excess chloride induced both photolabilization and photo-oxidation of Cl-and/or H,O ligands. Photolabilization produces the formation of reaction intermediates identified as
Hydrogen generation m photolysis of aqueous solutions of acetic acid in the presence of copper(II) chloride
✍ Scribed by K. Tennakone; U.S. Ketipearachchi; S. Punchihewa; W.A.C. Perera; R. Tantrigoda
- Publisher
- Elsevier Science
- Year
- 1991
- Weight
- 248 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0304-5102
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## Abstract The flash photolysis of the mono and di‐thiocyanate complexes of μ‐oxo __bis__(oxo‐molybdenum(V)) (Mo~2~O~4~(NCS)~__x__~(H~2~O)~6−__x__~^(2−__x__)+^ where __x__ = 1, 2) has been studied in the system composed of perchloric acid solutions of Mo~2~O~4~(H~2~O)~6~^2+^ in the presence of exc