Hydrogen exchange rates on nickel by chromatography
✍ Scribed by Motoyuki Suzuki; J.M. Smith
- Book ID
- 113174179
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 628 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0021-9517
No coin nor oath required. For personal study only.
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The hydrogen-deuterium exchange reactions of methane in a deuterium stream were studied by a pulse experiment over a reduced nickel catalyst. The reduced nickel (Ni1373) prepared from nickel oxide calcined at 1373 K had a higher activity than the reduced nickel (Ni773) prepared from the nickel oxide
A cross experiment with a specifically labeled hydrocarbon reveals that intramolecular hydrogen exchange is an important process for saturated hydrocarbons chemisorbed on a nickel catalyst. Attack of unactivated C-H bonds represents the initial step of most important technical processes such as petr