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Hydrogen evolution catalyzed by Fe4S4-albumin as a hydrogenase model

✍ Scribed by Ichiro Okura; Satoshi Nakamura

Publisher
Elsevier Science
Year
1980
Weight
166 KB
Volume
9
Category
Article
ISSN
0304-5102

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## Abstract A high‐spin model of nitrogenase with a Fe~8~S~9~X^+^ cluster (X = nitrogen or carbon) is used to test a mechanism for molecular hydrogen production, which is known to accompany ammonia production. The reaction proceeds with a series of protonation‐reduction (PR) steps which are conside