The chemisorption of hydrogen on positively charged vanadium clusters, Vi (n = l-17), was studied by measuring reaction rates and saturation coverages. Vanadium clusters are produced by laser vaporization and are injected into a Penning trap. Rates of the reaction Vi +HZ -Vi HZ are measured by axial
β¦ LIBER β¦
Hydrogen chemisorption on, and diffusion through, palladium clusters
β Scribed by N. A. Baykara; J. Andzelm; D. R. Salahub; S. Z. Baykara
- Publisher
- John Wiley and Sons
- Year
- 1986
- Tongue
- English
- Weight
- 421 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0020-7608
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## Abstract The analysis of nonadditive effects in small palladium clusters via LCAOβMOβSCF calculations using the nonempirical pseudopotential model is presented. The results are tentatively correlated with previous studies on various metal clusters (Li, Be, Mg, etc.) for which a good knowledge of