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Hydrogen Bonding vs Steric Gearing in a Hexasubstituted Benzene

✍ Scribed by Gavette, Jesse V.; Sargent, Andrew L.; Allen, William E.

Book ID
120285030
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
180 KB
Volume
73
Category
Article
ISSN
0022-3263

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Conformational analysis / "Push-pull" interaction / Benzene ring, deformation to boat and twist-boat forms / ## Calculations, AM1 The X-ray analyses of three 1,3,5-tris(alkylamino)-2,4,6-trinitrobenzenes (alkyl = iPr, neopentyl, t B u 1 df) show their benzene rings to be highly distorted towards