𝔖 Bobbio Scriptorium
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Hydrogen bonding to the nitroxide of protein bound spin labels

✍ Scribed by Urban, Leszek; Steinhoff, Heinz-Jürgen

Book ID
121708599
Publisher
Taylor and Francis Group
Year
2013
Tongue
English
Weight
516 KB
Volume
111
Category
Article
ISSN
0026-8976

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Polarity Contributions to Hyperfine Spli
Polarity Contributions to Hyperfine Splittings of Hydrogen-Bonded Nitroxides—The Microenvironment of Spin Labels
✍ Derek Marsh 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 108 KB

A self-consistent treatment of reaction field effects on isotropic (14)N hyperfine coupling constants of nitroxide spin labels in mixtures of polar and apolar solvents is given based on the Onsager approach. It is shown that this works reasonably well for mixtures of water or methanol with dioxane,