Hydrogen bonding monitored by deuterium isotope effects on carbonyl 13C chemical shift in BPTI: intra-residue hydrogen bonds in antiparallel β-sheet
✍ Scribed by Erik Tüchsen; Poul Erik Hansen
- Book ID
- 119070392
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 653 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0141-8130
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## Abstract A new class of compounds, the 2‐hydroxythioacetophenones, and related compounds have recently been synthesized. The hydrogen‐bond system has been characterized by NMR chemical shifts and deuterium isotope effects on these as well as by DFT calculations. Use of solid‐state ^13^C NMR has
Deuterium-induced chemical shift differences on the 13C (DIS) are reported for a series of Schiff bases of salicylaldehydes, l-(phenyliminomethyl)naphthalen-2-ol and 4-chloro-1,7-phenanthrolin-l0-ol. Provided that corrections for the hydrogen donor atom and diamagnetic effects of the surrounding gro