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Hydrogen bonding. III. Tetrapropylammonium hydrogen difluoride and the thermal elimination reaction of tetrapropylammonium fluoride hydrates

โœ Scribed by Harmon, Kenneth M.; Gennick, Irene; Madeira, Susan L.; Duffy, Dorothy L.


Book ID
126158726
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
325 KB
Volume
39
Category
Article
ISSN
0022-3263

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A kinetic study of the thermal eliminati
โœ J. A. Kerr; D. M. Timlin ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 619 KB

The kinetics of the thermal elimination of H F from 1,2-difluoroethane CHzFCHzF -+ CHz=CHF + H F have been studied in a static system over the temperature range 734-820'K. was shown to be first order and homogeneous, with a rate constant of The reaction log kz(s-l) = 13.39 f 0.2 -(62.9 f 0.9)/0 wher