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Hydrogen bonding and molecular association in 2-(quinuclidinium)-butyric acid bromide hydrate studied by X-ray diffraction, DFT calculations, FTIR and NMR spectroscopy, and potentiometric titration

✍ Scribed by Z. Dega-Szafran; A. Katrusiak; M. Szafran; P. Barczyński


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
720 KB
Volume
975
Category
Article
ISSN
0022-2860

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The crystals of bis(homarine)hydrogen perchlorate, (HOM) 2 HAEClO 4 , (1) are orthorhombic, space group C2/c, with a pair of HOM molecules bridged by a symmetrical OAEHAEO hydrogen bond of 2.480(3) A ˚. In the homoconjugated cation, (HOMAEHAEHOM) + , the H-bonded proton is in centre of inversion. Th