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Hydrogen Bonding and Ionization of Carboxylic Acids in Aqueous Solutions

✍ Scribed by Katchalsky, A.; Eisenberg, H.; Lifson, S.


Book ID
121700377
Publisher
American Chemical Society
Year
1951
Tongue
English
Weight
266 KB
Volume
73
Category
Article
ISSN
0002-7863

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Low-Barrier Hydrogen Bonding in Aqueous
✍ Constance S. Cassidy; Jing Lin; John B. Tobin; Perry A. Frey πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 English βš– 143 KB

We present additional spectroscopic evidence for the formation of low-barrier hydrogen bonds (LBHBs) within vicinal and geminal dicarboxylic acid monoanions. Hydrogen ciscyclohexane 1,2-dicarboxylate, displays low-field 1 H NMR signals in aprotic solvents at 19.3 to 19.7 ppm, depending on the solven