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Hydrogen bonding and dissociation effects on the gas phase proton transfer reactions of ozone

✍ Scribed by R. Contreras; V. S. Safont; J. Andrés; P. Pérez; A. Aizman; O. Tapia


Publisher
Springer
Year
1998
Tongue
English
Weight
156 KB
Volume
99
Category
Article
ISSN
1432-2234

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Effects of ring strain on gas-phase rate
✍ Roger Atkinson; Sara M. Aschmann; William P. L. Carter; James N. Pitts Jr. 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 517 KB

Rate constants for the gas-phase reactions of 0 3 with a series of cycloalkenes and with cis-2-butene have been determined at 297 f 1 K. The rate constants obtained were (in units of cm3/molecule-s): cis-2-butene, 1.38 f 0.16; cyclopentene, 2.75 f 0.33; cyclohexene, 1.04 f 0.14; cycloheptene, 3.19 f