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Hydrogen bonding and conformational effects on13 chemical shifts of hydroxybenzaldehydes in the solid state

✍ Scribed by F. Imasihro; S. Maeda; K. Takegoshi; T. Terao; A. Saika

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 286 KB
Volume: 99
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)80557-0

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✦ Synopsis

In high-resolution solidstate CP/MAS 13C NhfR spectra of several hydrosybenzaldehydes, the downfield shifts due to hydrogen bonding for the carbonyl carbons are found to vary inversely with the O...O hydrogen-bond distances_ Conformations of the aldehyde groups in the solid state are determined by the chemical shifts of the ortho carbons.

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