Hydrogen Bonded OH-Stretching Vibration in the Water Dimer
β Scribed by Schofield, Daniel P.; Lane, Joseph R.; Kjaergaard, Henrik G.
- Book ID
- 126824776
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 67 KB
- Volume
- 111
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
A theory for vibrational predissociation of hydrogen-bonded OH...0 complexes via OH stretch-00 stretch energy transfer is constructed, motivated by a recent experiment on vibrational predissociation of hydrogen-bonded ethanol dimer in solution. The theory employs a vibrationally adiabatic perspectiv
Spectral diffusion in the OH stretching (m OH ) band of water is studied by ultrafast IR-Raman spectroscopy. The m OH transition consists of two overlapping inhomogeneously broadened subbands, a broader ($500 cm Γ1 ) redshifted band and a smaller, narrower ($200 cm Γ1 ) blueshifted band. The blueshi