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Hydrogen-Bonded Helices in Crystals with Prescribed Organization

✍ Scribed by Radu Custelcean; Michael D. Ward

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
158 KB
Volume
114
Category
Article
ISSN
0044-8249

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In this Communication, the structures of the d-and l-amino acid naphthalenediimide (NDI) derivatives in Scheme 1 were inadvertently interchanged. The correct scheme is shown below. Scheme 1. Amino acid NDI derivatives. Boc = tert-butyloxycarbonyl, Bzl = benzyl, Trt = trityl.

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The intramolecular helix backbone C O ---H-N hydrogen Ž . bonding energies in poly L-alanine ␣ helices have been estimated both in vacuum and in an aqueous environment using the parameter sets of five of the most commonly used force fields for modeling biomolecules, namely AMBER, CHARMM, ECEPP, GROM