Hydrogen-bonded complex formation of oximes with carboxylic acids and with amides. (E)-Acetophenone oxime–benzoic acid (1/1) and (E)-benzaldehyde oxime–benzamide (1/1)
✍ Scribed by Maurin, J. K. ;Winnicka-Maurin, M. ;Paul, I. C. ;Curtin, D. Y.
- Book ID
- 114514871
- Publisher
- International Union of Crystallography
- Year
- 1993
- Tongue
- English
- Weight
- 741 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0108-7681
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1 H and 15 N NMR spectra of 10 complexes exhibiting strong OHN hydrogen bonds formed by 15 N-labeled collidine and different proton donors, partially deuterated in mobile proton sites, have been observed by low-temperature NMR spectroscopy using a low-freezing CDF 3 /CDF 2 Cl mixture as polar aproti
A novel series of hydrogen-bonded solid 1 : 1 acid-base complexes of 15 N-labeled 2,4,6-trimethylpyridine (collidine) with carboxylic acids and their hydrogen bond deuterated analogs were synthesized and studied by 1 H magic angle spinning (MAS) and 15 N cross-polarization NMR with and without MAS.