Hydrogen Bond Networks

✍ Scribed by C. A. Angell, C. Alba-Simionesco, J. Fan, J. L. Green (auth.), Marie-Claire Bellissent-Funel, John C. Dore (eds.)

• Publisher: Springer Netherlands
• Year: 1994
• Tongue: English
• Leaves: 564
• Series: NATO ASI Series 435
• Edition: 1
• Category: Library

✦ Synopsis

The almost universal presence of water in our everyday lives and the very `common' nature of its presence and properties possibly deflects attention from the fact that it has a number of very unusual characteristics which, furthermore, are found to be extremely sensitive to physical parameters, chemical environment and other influences. Hydrogen-bonding effects, too, are not restricted to water, so it is necessary to investigate other systems as well, in order to understand the characteristics in a wider context. HydrogenBond Networks reflects the diversity and relevance of water in subjects ranging from the fundamentals of condensed matter physics, through aspects of chemical reactivity to structure and function in biological systems.

✦ Table of Contents

Front Matter....Pages i-xxiii
Front Matter....Pages 1-2
Hydrogen Bonding and the Fragility of Supercooled Liquids and Biopolymers....Pages 3-22
Hydrogen Bonding and Molecular Mobility in Aqueous Systems....Pages 23-35
Structural and Dynamical Quantum Effects in Aqueous Solution....Pages 37-51
Novel Features in the Equation of State of Metastable Water....Pages 53-60
The Role of H-Bond in the Formation of Ices....Pages 61-67
Radial Distribution Function of Heavy Water Steam....Pages 69-72
Molecular Dynamics on a Water Model with Polarizability and Hyperpolarizability....Pages 73-76
MD Simulations of Stretched TIP4P-Water in the Supercooled Regime....Pages 77-80
Anomalous Sound Dispersion in Liquid Water....Pages 81-84
Sound Propagation in Hydrogen Bonded Molecular Liquids: The Case of Liquid Water....Pages 85-95
Orientational Correlations in Hydrogen Bonded Networks....Pages 97-112
Are Hydrogen Bonds Present in Hydrogen Halides Liquids Other Than HF?....Pages 113-118
Investigation of the Structure of Liquid Formic Acid....Pages 119-127
Front Matter....Pages 129-130
Incoherent Inelastic Neutron Scattering from Liquid Water: A Computer Simulation Study....Pages 131-138
The Observation of Different Strengths of H-Bonds in Ices....Pages 139-148
IR Spectra and Dynamics of H 2 O (D 2 O, HDO) Molecules in a Still Poorly Known Liquid: Water....Pages 149-168
Low-Frequency Raman Spectra from Anhydrous Sulfuric and Chlorosulfonic Acids, and Liquid Water—Disruption of Tetrahedral Hydrogen Bonding—Relation to Water Structure....Pages 169-179
Picosecond Holeburning Spectroscopy in the Infrared of Water and other Hydrogen-Bonded Systems....Pages 181-195
Low Frequency Raman Spectra in Water by Normal Mode Analysis....Pages 197-203
Light Scattering from Liquid Water....Pages 205-220
Front Matter....Pages 129-130
Dielectric Properties of Aqueous Solutions....Pages 221-230
Formic Acid, Ethanol in Vycor Glass, and Water in Aluminosilicate Zeolites....Pages 231-238
Application of the Reactive Flux Formalism to Study Water Hydrogen Bond Dynamics....Pages 239-246
Temperature Dependence of Ion Solvation Dynamics in Liquid Water....Pages 247-250
Theoretical Simulation of OH and OD Stretching Bands of Isotopically Diluted HDO Molecules in Lithium Formate Solution....Pages 251-254
Influence of water molecules on the nucleation rate of polymorphic complexes with different conformations in solution....Pages 255-259
Hydrogen Bond Nature in Solids Based on Nuclear Quadrupole Resonance Spectroscopy Studies....Pages 261-280
Simulation of Liquid Mixtures....Pages 281-304
Front Matter....Pages 305-306
Structure and Dynamics of Water in Confined Geometry....Pages 307-336
Structure and Dynamics of Water at Interfaces....Pages 337-338
Hydrogen Bond Solids in Space....Pages 339-354
Hyperquenched Glassy Bulk Water: A Comparison with Other Amorphous Forms of Water, and with Vitreous but Freezable Water in a Hydrogel and on Hydrated Methemoglobin....Pages 355-372
Spectroscopic and Simulation Study of Ice Surfaces: Bare and with Adsorbates....Pages 373-380
A Structural Study of Vapour Deposited Amorphous Ice by Neutron Diffraction....Pages 381-388
Hydrogen Bonds Reorganisation during Clathrate Hydrate Growth in Hexagonal Ice....Pages 389-393
Langmuir Films of Amphiphilic Alcohols and Surfaces of Polar Crystals as Templates for Ice Nucleation....Pages 395-402
Structural Studies of Ice Nucleation in Confined Geometries....Pages 403-409
Crystal ab initio Investigations of Ice II, VIII and IX....Pages 411-418
Water in Mesoscopic Hydrophobic Confinements....Pages 419-424
Structure and Dynamic Properties of Water Confined in Small Volumes....Pages 425-432
Front Matter....Pages 305-306
Water Dynamics in Porous Biopolymer Networks: Data of Neutron Experiments....Pages 433-439
Tg Regulation Effects in Polymer-Water Systems....Pages 441-445
Role of Water Molecules in the Growth of Nanosize Particles in Reverse Micelles....Pages 447-454
Front Matter....Pages 455-456
Physical Origin and Biological Significance of Solvent Induced Forces....Pages 457-479
Structure and Dynamics of Aqueous Solutions of Tetramethylurea....Pages 481-488
Structure, Dynamics and Function of Hydrogen-Bonded Networks in Proteins and Related Systems....Pages 489-508
Hydration and Association Abilities of Cytidine, 2’-Deoxycytidine and Their Phosphate Salts in the Aqueous Solutions by Molecular Dynamics Simulations and FTIR Spectroscopy....Pages 509-512
Dynamics of Water Confined in Aqueous Gels....Pages 513-520
Self-trapped States in Chains of Hydrogen-Bonded Molecules: Optical Measurements, Neutron Scattering and Diffraction....Pages 521-528
Fibrous Biopolymers: New Experimental Approaches Using Pulsed-Source Neutron Techniques....Pages 529-532
Front Matter....Pages 533-534
Workshop A: Simulations, Predictions and Experimental Observations for Water Structure....Pages 535-536
Workshop session on experimental investigation of structural and dynamic features in varying conditions....Pages 537-537
Role of the H-Bond Network of Water in Biological Structures and Systems....Pages 539-542
Concluding Remarks....Pages 543-544
Back Matter....Pages 545-558

✦ Subjects

Condensed Matter Physics; Physical Chemistry; Biochemistry, general; Surfaces and Interfaces, Thin Films