Hydrogen bond effect on the structure and vibrational spectra of complementary pairs of nucleic acid bases. III. Guanine-cytosine
β Scribed by G. N. Ten, A. A. Yakovleva, V. V. Nechaev, V. I. Baranov
- Book ID
- 119882464
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2012
- Tongue
- English
- Weight
- 350 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0022-4766
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The enthalpy of hydrogen-bond formation between guanine (G) and cytusine (C) in o-dichlorobenzene and in chloroform at 25Β°C has been determined by direct calorimetric measurement. We derivatized 2'-deoxyguanosine and 2'-deoxycytidine at the 5'-and 3'-hydroxyls with triisopropylsilyl groups; these gr
For the first hydrogen bond of the guanine-cytosine (G-C) pair, the potential function V(r, R ) is found for the nonequilibrium bond length R. A new form of the semiempirical potential function, Clementi's calculations for V ( r , R,) and some experimental data are used. New wave functions and energ