A study of hydrogen-bond dynamics in car
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T. Agaki; F. Imashiro; T. Terao; N. Hirota; S. Hayashi
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Article
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1987
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Elsevier Science
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English
β 516 KB
Proton (deuteron) transfer ofhydrogen bonds in benzoic, glutark and pformylbenzoic acids was studied by proton (deuteron) T, measurements. Deuteration of carboxylic protons was found to increase the barriers to classical proton jumping as well as quantum-mechanical tunneling. The former barriers inc