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Hydrogen atom transfer reactions: the nature of the transition state as delineated from the temperature dependence of the primary KIE

โœ Scribed by Strong, Henry L.; Brownawell, Marilyn L.; Filippo, Joseph San


Book ID
121421473
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
350 KB
Volume
105
Category
Article
ISSN
0002-7863

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Kinetic study of gas-phase reactions wit
โœ R. A. Taccone; O. Salinovich; E. H. Staricco ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 573 KB

The following gas-phase reactions: (1) ( 2 ) were studied by the competitive method with CF,I as the source of radicals. The kinetic parameters obtained in the temperature range 533-613 K and 503-613 K respectively for chlorine atom transfer reactions are given by: log hl/h,"(cm3 mol-" s -") = 16