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Hydrogen atom transfer in the reactions of thermally-generated di-t-alkylketyl and 1-adamantyl radicals

✍ Scribed by John S. Lomas; Sylvette Briand

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 226 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)80288-4

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✦ Synopsis

In the thermolysis of tri-(1-adamantyl)methanol about 55% of the di-(l-adamantyl)ketyl and l-adamantyl radicals escape from the solvent cage, the former transferring hydrogen to benzophenone and the second abstracting hydrogen from the solvent,

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