Hydrogen Atom Release Dynamics in Radical–Radical Reactions: Saturated vs Unsaturated
✍ Scribed by Sung-Eui Youn; You-Hwa Ok; Jong-Ho Choi
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 235 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1439-4235
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📜 SIMILAR VOLUMES
## Abstract The dual‐level direct dynamics approach is employed to study the dynamics of the CH~3~OCH~3~ + H (R1) and CH~3~OCH~3~ + CH~3~ (R2) reactions. Low‐level calculations of the potential energy surface are carried out at the MP2/6‐311+G(d,p) level of theory. High‐level energetic information
An excellent substrate of methylmalonyl-CoA mutase, methylmalonyl-carba-(dethia) coenzyme A (methylmalonyl-CH(2)-CoA), was synthesized by a chemoenzymatic method and its alpha-proton was exchanged with deuterium by long-term incubation in deuterium oxide at pH 6.9. After addition of highly purified
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