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Hydrogen Atom Adducts to Nitrobenzene: Formation of the Phenylnitronic Radical in the Gas Phase and Energetics of Wheland Intermediates

✍ Scribed by Polášek, Miroslav; Tureček, František

Book ID
120343541
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
195 KB
Volume
122
Category
Article
ISSN
0002-7863

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Addition of hot hydrogen atoms to 1-bute
Addition of hot hydrogen atoms to 1-butene in the gas phase and dissociation of excited butyl radicals
✍ Janusz Gawłowski; Jan Niedzielski 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 English ⚖ 619 KB

## Abstract The reaction of hot hydrogen atoms originating from 253.7‐ and 228.8‐nm photolyses of hydrogen sulfide with 1‐butene was investigated. Of the hydrogen atoms undergoing addition a substantial part undergoes it in a first collision (37 and 48% at 253.7 and 228.8 nm, respectively) yielding