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Hydrogen-atom abstraction from methane by stoichiometric early transition metal oxide cluster cations

✍ Scribed by Zhao, Yan-Xia; Wu, Xiao-Nan; Wang, Zhe-Chen; He, Sheng-Gui; Ding, Xun-Lei

Book ID: 124082337
Publisher: Royal Society of Chemistry
Year: 2010
Tongue: English
Weight: 577 KB
Volume: 46
Category: Article
ISSN: 1359-7345
DOI: 10.1039/B924603G

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## Abstract Vanadium–silicon heteronuclear oxide cluster cations were prepared by laser ablation of a V/Si mixed sample in an O~2~ background. Reactions of the heteronuclear oxide cations with methane in a fast‐flow reactor were studied with a time‐of‐flight (TOF) mass spectrometer to detect the cl

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