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Hydrogen adsorption on C3H3–TM (TM

✍ Scribed by N. Wadnerkar; V. Kalamse; A. Chaudhari

Book ID
125848486
Publisher
Springer
Year
2012
Tongue
English
Weight
282 KB
Volume
24
Category
Article
ISSN
1040-0400

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✍ Michael F. Lappert; Marcus Layh 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 194 KB

Treatment of LiC(TMS)3(THF)2 with the nitrile 4-RC6H4CN in Et20 at ambient temperature yields the new lithium 1-aza-allyl I][N(TMS)C(C6H4R-4)C(TMS)2](THF ) which readily eliminates LiN(TMS)2 upon heating in refluxing benzene yielding the acetylene 4-RC6H4C=-C(TMS) in quantitative (TMS = SiMe3; R = H