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Hydrogen abstraction reactions from organosilicon compounds. The reactions of fluoromethyl radicals with trichlorosilane. The photolyses of di- and tetrafluoroacetone

✍ Scribed by J. A. Kerr; D. M. Timlin

Publisher: John Wiley and Sons
Year: 1971
Tongue: English
Weight: 638 KB
Volume: 3
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550030102

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✦ Synopsis

The photolyses of 1,3-difluoro-and 1,1,3,3-tetrafluoroacetone have been reinvestigated as sources of fluoromethyl radicals, and the following rate constant ratios were determined: (1) (2) 2CHzF + CHZFCH*F* CHzF + CHzFCOCHzF -+ CHsF + CHFCOCHzF log kl/k21~2 = (3.6 f 0.1) -[(7.6 + 0.2)/0]$

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