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Hydrogen abstraction by triplet ketones: Applicability of the electronic-vibrational energy transfer model

✍ Scribed by R.W. Yip; W. Siebrand

Publisher: Elsevier Science
Year: 1972
Tongue: English
Weight: 458 KB
Volume: 13
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(72)85043-7

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✦ Synopsis

A critical comparison is made between a theoretical model for photochemical reactions based on their analogy with radiationless transitions and the experimental data on hydrogen abstraction by excited ketones in solution. It is concluded that rapid vibrational energy redistribution tends to rule out mcchanisrns based on energy transfer to a particular vibrational mode, except in I&v-pressure gases.

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