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Hydroformylation of norbornene and 2,5-norbornadiene catalysed by platinum(0)-alkene complexes in the presence of methanesulfonic acid: determination of the stereochemistry of the reaction

✍ Scribed by C. Botteghi; S. Paganelli; A. Perosa; R. Lazzaroni; G. Uccello-Barretta


Book ID
107812433
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
516 KB
Volume
447
Category
Article
ISSN
0022-328X

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In aqueous solution, bis(nucleoside) complexes formed by the reaction of cis-[Pt(NH3)2(H2O)2]2+ with an excess of either adenosine (ado) or a mixture of adenosine and guanosine (guo) undergo a slow N7--> N1 linkage isomerisation in the adenine moiety. The isomerisation probably involves the breaking