Hydroformylation of 1-Octene in Supercritical Carbon Dioxide and Organic Solvents using Trifluoromethyl-Substituted Triphenylphosphine Ligands

Selectivity of Rhodium-Catalyzed Hydrofo

Selectivity of Rhodium-Catalyzed Hydroformylation of 1-Octene during Batch and Semi-Batch Reaction using Trifluoromethyl-Substituted Ligands

✍ Ard C. J. Koeken; Michiel C. A. van Vliet; Leo J. P. van den Broeke; Berth-Jan D 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 377 KB

## Abstract The regioselectivity of catalysts generated __in situ__ from dicarbonyl rhodium(I)(2,4‐pentanedione) and trifluoromethyl‐substituted triphenylphosphine ligands has been evaluated during the hydroformylation of 1‐octene. The influence of batch or semi‐batch operation, the solvent, and th