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Hydroformylation of 1 -aryl- 1 -(2-pyridyl) ethenes catalyzed by rhodium complexes

✍ Scribed by Carlo Botteghi; Stefano Paganelli; Laura Bigini; Mauro Marchetti

Publisher
Elsevier Science
Year
1994
Weight
552 KB
Volume
93
Category
Article
ISSN
0304-5102

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πŸ“œ SIMILAR VOLUMES

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SiO 2 -tethered rhodium complexes deriving from Rh(CO) 2 acac and the commercially available 3-(mercapto)propyl-and 3-(1thioureido)propyl-functionalyzed silica gel, respectively, have been used as catalysts in the hydroformylation of some functionalized olefins directed to the preparation of interme

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Proposed as intermediates in the catalytic oxidation of olefins to ketones, 3-rhoda-1,2-dioxolanes (ΞΊ C ,O -2-peroxyethyl rhodium complexes) have now been prepared by oxygenation of solid [(N -ligand)Rh (ethene)]PF with air. This process leads to stable isomeric 3-rhoda-1,2-dioxolanes A and B. Upon