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Hydroformylation Catalyzed by Rhodium/Fluorinated Triarylphosphite Complexes in Fluorous Biphasic Media

✍ Scribed by Eric Monflier; Andre Mortreux; Yves Castanet


Publisher
John Wiley and Sons
Year
2006
Weight
8 KB
Volume
37
Category
Article
ISSN
0931-7597

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Rhodium-Catalyzed Hydrogenation of Alken
✍ Denis Sinou; David Maillard; Ali Aghmiz; Annaβ€…M. Masdeuβ€…i-BultΓ³ πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 143 KB πŸ‘ 1 views

The reaction of [Ir(m-Cl)(COD)] 2 with various fluorous derivatives of triphenylphosphane containing a para-, meta-, or ortho-(1H,1H-perfluoroalkoxy)-substituted fluorous phosphane P(C 6 H 4 -ORf) 3 (Rf CH 2 C 7 F 15 , CH 2 CH 2 CH 2 C 8 F 17 ) and CO (1 atm) gives the corresponding trans-[Ir(m-Cl)(