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Hydrodynamical behaviour of the poly(ethylene oxide)-sodium dodecylsulphate complex

✍ Scribed by J. Francois; J. Dayantis; J. Sabbadin


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
711 KB
Volume
21
Category
Article
ISSN
0014-3057

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✦ Synopsis


We have studied by various methods (conductimetry, ionic activity measurement, viscometry, ultracentrifugation) the formation of poly(ethylene oxide)-sodium dodecylsulphate complex, focusing attention on the influence of polymer molecular weight. The net charge of the complex is calculated and its hydrodynamical behaviour is compared to that of a simple polyelectrolyte of the same charge density. The molecular weight dependence of the intrinsic viscosity is of the classical Mark-Houwink form.


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## NOTE First Evidence of Poly(ethylene oxide)-Mixed Sodium Dodecyl Sulfate/Sodium Decyl Phosphate Complexes the absence of NaDeP in PEO binding, and reports conductometric and kinetic results of ideal mixing of SDS and NaDeP for PEO. Polymer-mixed surfactant complex formation among poly(ethylene