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Hydrodynamic properties of A8B8 type miktoarm (Vergina) stars

โœ Scribed by Stergios Pispas; Apostolos Avgeropoulos; Nikos Hadjichristidis; Jacques Roovers


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
111 KB
Volume
37
Category
Article
ISSN
0887-6266

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โœฆ Synopsis


The dilute solution properties of three (PS) 8 (PI) 8 miktoarm (Vergina) stars were investigated by viscometry and dynamic light scattering in toluene and tetrahydrofuran (THF) (common good solvents), cyclohexane at 34.5ยฐC (theta solvent for PS and good for PI) and dioxane at 34ยฐC (theta solvent for PI and good for PS). Experimental intrinsic viscosity [] and hydrodynamic radii, R h , values in all solvents were larger for the miktoarm stars in comparison to the calculated ones using a simple model which describes the size of the copolymers as a weighted average of the sizes of the homopolymer stars with the same total molecular weight and number of arms as the copolymer. This expansion is discussed on the basis of the increased number of heterocontacts, the topological constrains imposed by the common junction point in this highly branched miktoarm architecture and the asymmetry in molecular weights of the different kinds of arms. The conformation adopted in dilute solutions can explain, to some extent, the morphological results obtained on the same materials. The ratios of viscometric to hydrodynamic radii are consistent with previous investigations on linear and star polymers and in accord with the hard sphere model.


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