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Hydrocarbonylation of Methyl Acetate Using a Homogeneous Rh(CO)Cl(PPh 3 ) 2 Complex as a Catalyst Precursor: Kinetic Modeling

โœ Scribed by Kelkar, Ashutosh A.; Jaganathan, Rengaswamy; Chaudhari, Raghunath V.

Book ID
127233182
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
92 KB
Volume
40
Category
Article
ISSN
0888-5885

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Hydroesterification of cyclohexene using
Hydroesterification of cyclohexene using the complex Pd(PPh3)2(TsO)2 as catalyst precursor: Effect of a hydrogen source (TsOH, H2O) on the TOF and a kinetic study (TsOH: p-toluenesulfonic acid)
โœ Andrea Vavasori; Luigi Toniolo; Gianni Cavinato ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 194 KB

The hydroesterification of cyclohexene is catalyzed by a preformed Pd(PPh 3 ) 2 (TsO) 2 complex I in methanol as solvent. The effect of PPh 3 , TsOH, and water on the TOF has been evaluated. The system I/PPh 3 /TsOH = 1/6/8, in the presence of 800 ppm of H 2 O, at 373 K and under 2.0 MPa of CO leads