Hydrocarbon oxidations with oxometalloporphinates. Isolation and reactions of a (porphinato)manganese(V) complex
โ Scribed by Groves, John T.; Kruper, William J.; Haushalter, Robert C.
- Book ID
- 120344222
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 349 KB
- Volume
- 102
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
## Abstract The intrinsic reactivity of a manganese(V)โoxo porphyrin complex, a typically fleeting intermediate in catalytic oxidation reactions in solution, has been elucidated in a study focused on its gasโphase ionโchemistry. The naked highโvalent Mn^V^โoxo porphyrin intermediate **1** ([(tpfpp)
Binuclear manganese complexes mimic the catalase enzyme by converting hydrogen peroxide rapidly and efficiently to oxygen and water. The complex (1) may be activated by either periodic acid or Oxone ยฎ and can oxidize selected organic substrates. Potassium manganate gave similar oxidation products su