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Hydrocarbon ignition in the presence of metal oxides

✍ Scribed by G.H Meguerian; F.W Rakowsky

Publisher
Elsevier Science
Year
1967
Tongue
English
Weight
359 KB
Volume
11
Category
Article
ISSN
0010-2180

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✦ Synopsis

Am~'ric-'m Oil Comoan3, Whiting. Indiana 1 he effects of lea .L ~:opper aJJJ Β’obal! 0xidcs upon the ign,t~on kinet:cs of mi.~ lures of n-heplanc with iso.4,ctar~Β’ anal toluene have been sltadie~d it, a flo~' .%~;ste~. lgl~itio~. ~mperatures ~'ere corre|ateO wi~h initial fuel ~nd oxy$ct! cx'~fl-ccmra~ions fore: ch fuel and oxide by an Arrhenius-lype feint/on. The ~gniiion ofparaffi.nic fuel is probabl5 Β’omroiMd by dee rate of H_,O. production By increasing the rate of I-leO2 decomposition, all theeΒ’ oxides it,hibi| igni~m rear;ions In do;ng .~o. lead monoxide apparently remains unchanged, whereas cupric oxide and cobait~c ox~l~ appear It) undergo oxidation-reduction reuction~ be~cvn lower and higher oxides Subsli~ulioti of tohtenc f.,Β’ iso-octa~c in m~xture~; ,~ith *t.heptt.nΒ’ doex nc*~ alter ~he igrtition t'nechamsm.

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## Effects of group IIB metal oxides (viz., ZnO, CdO, and HgO) on ethylene thiourea (ETU) accelerated the curing of acrylic rubber (ACM) have been evaluated with a view to elucidate the cross-linking mechanism with special reference to the role of metal oxides. Best results are obtained with CdO i