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Hydroborations: A New Route for the Preparation of 1-Alkyl- (or Aryl) 2-Tetralones

โœ Scribed by Serge Kirkiacharian, B. ;Koutsourakis, Pantelis G.


Book ID
120390264
Publisher
Taylor and Francis Group
Year
1993
Tongue
English
Weight
203 KB
Volume
23
Category
Article
ISSN
0039-7911

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Hydroboration of mono-substituted allene
โœ Gowriswari Narla; Herbert C. Brown ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 221 KB

Hydroboration of mono-substituted allenes with Chx2BH at 0 \*(2 leads to the corresponding (E)substituted allylboranes, known as higher crotylboranes, exclusively. These higher cmtylboranes react with aldehydes, and on oxidation, provide the corresponding anti.3.alkyl/aryl-4.hydroxy-l-alkenes in hig