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Hydroboration. XXXI. Cyclic hydroboration of dienes with borane in tetrahydrofuran in the molar ratio of 1:1

โœ Scribed by Brown, Herbert C.; Negishi, Eiichi; Burke, Patrick L.


Book ID
127283178
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
828 KB
Volume
94
Category
Article
ISSN
0002-7863

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1,2 Asymmetric induction in the cyclic h
โœ David J. Morgans Jr. ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 236 KB

## Cyclic hydroboration of an appropriately substituted 1.5~diene yields a 1,5 dial as the major product which can be converted to the racemic Prelog-Djerassi lactone. The widespread occurrence of the three carbon unit 1 in natural products of current synthetic interest has prompted us to investig