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Hydroboration and Oxymercuration of Some 1-Substituted Norborn-2-enes

✍ Scribed by Wolfgang Luef; Ulrich-Christian Vögeli; Reinhart Keese

Publisher
John Wiley and Sons
Year
1983
Tongue
German
Weight
599 KB
Volume
66
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The 1‐substituted norborn‐2‐enes 11–13 and 18 react with electrophiles under kinetic control preferentially in 2‐position. The regioselectivity in oxymercuration is higher than in hydroboration and reaction with aqueous palladium chloride.

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