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Hydroboration. 92. Investigation of Practical Methods for the Synthesis of Optically Pure Isopinocampheylchloroborane for the Asymmetric Hydroboration of Representative Prochiral Alkenes

โœ Scribed by Kulkarni, Shekhar V.; Brown, Herbert C.


Book ID
127157463
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
346 KB
Volume
61
Category
Article
ISSN
0022-3263

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Isopinocampheylbromoborane, a new promis
โœ Ulhas P. Dhokte; Herbert C. Brown ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 253 KB

A new promising in situ generated hydroborating agent, isopinocampheylbromoborane (IpcBHBr), achieves the asymmetric hydroboration of representative prochiral alkenes in pentane at lower temperatures, even at -78 ยฐC, than has been possible with isopinocampheylborane (IpcBH2) and isopinocampheylchlor