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Hydriodic Acid Reduction of α-Ketol and α-Diketo Fatty Acids

✍ Scribed by Osman, S. M. ;Ahmad, M.

Publisher
John Wiley and Sons
Year
1970
Weight
339 KB
Volume
72
Category
Article
ISSN
0931-5985

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✦ Synopsis

Abstract

The hydriodic acid reduction of α‐ketol and α‐diketo derivatives of three monoethenoid fatty acids, oleic, petroselinic and erucic acids, has been studied. The formation of an isomeric mixture of monoketo acids in each has been established by characterization of monocarboxylic or dicarboxylic acids, the hydrolysed fragments of Beckmann rearrangement of the corresponding oximes of monoketo acids, by thin‐layer chromatography (TLC). Hydriodic acid has been found to be a satisfactory reagent for the synthesis of monoketo acids from the α‐ketol and α‐diketo acids.

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