Hydrogenation of Crotonaldehyde and Acetaldol with Modified Pd‐Supported Catalysts. II. On the Influence of a Chromium Modification of Pd/Al~2~O~3~ Catalysts The catalytic properties in hydrogenation reactions on chromium containing Pd/Al~2~O~3~ catalysts are influenced by an “esemble effect.” The
Hydrierung von Crotonaldehyd, Butyraldehyd und Acetaldol mit modifizierten Ni-Trägerkatalysatoren. I. Zum Einfluß einer Kupfermodifizierung auf Ni/Kaolin-Katalysatoren
✍ Scribed by Dr. D. Bohm; Dipl.-Chem. J. Hamann; Prof. Dr. P. Kripylo
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- English
- Weight
- 457 KB
- Volume
- 332
- Category
- Article
- ISSN
- 1615-4150
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✦ Synopsis
Hydrogenation of Crotonaldehyde, Butyraldehyde and Acetaldole with Modified Ni Carrier Catalysts. I. On the Influence of a Copper Modification of Ni/Kaolin Catalysts
The hydrogenation of crotonaldehyde, butyraldehyde and acetaldol in the presence of Ni‐Cu catalysts is a single‐centre reaction, whereas the decarbonylation of crotonaldehyde is a multi‐centre reaction. The ratio between the specific activities of the hydrogenation of the CC double bond and the carbonyl group is two. In the conversion of acetaldol the hydrogenolysis to butyraldehyde can be neglected in comparison with the hydrogenation to butan‐1,3‐diol.
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Hydrogenation of Crotonaldehyde and Acetaldole with Modified Pd Carrier Catalysts. I. On the Influence of a Titanium Modification to Pd/Al~2~O~3~ Catalysts The modification of Pd/Al~2~O~3~ catalysts with titanium was studied in the hydrogenation of crotonaldehyde and acetaldole. In the result of th