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Hydrierung von Crotonaldehyd, Butyraldehyd und Acetaldol mit modifizierten Ni-Trägerkatalysatoren. I. Zum Einfluß einer Kupfermodifizierung auf Ni/Kaolin-Katalysatoren

✍ Scribed by Dr. D. Bohm; Dipl.-Chem. J. Hamann; Prof. Dr. P. Kripylo


Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
457 KB
Volume
332
Category
Article
ISSN
1615-4150

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✦ Synopsis


Hydrogenation of Crotonaldehyde, Butyraldehyde and Acetaldole with Modified Ni Carrier Catalysts. I. On the Influence of a Copper Modification of Ni/Kaolin Catalysts

The hydrogenation of crotonaldehyde, butyraldehyde and acetaldol in the presence of Ni‐Cu catalysts is a single‐centre reaction, whereas the decarbonylation of crotonaldehyde is a multi‐centre reaction. The ratio between the specific activities of the hydrogenation of the CC double bond and the carbonyl group is two. In the conversion of acetaldol the hydrogenolysis to butyraldehyde can be neglected in comparison with the hydrogenation to butan‐1,3‐diol.


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