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Hydride transfer in the reactions of silicon hydrides with vinyl alkyl and simple ethers in the presence of iron pentacarbonyl

✍ Scribed by R. Kh. Freidlina; N. A. Kuz'mina; E. Ts. Chukovskaya

Book ID
112419828
Publisher
Springer
Year
1966
Tongue
English
Weight
218 KB
Volume
15
Category
Article
ISSN
1573-9171

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In the pursuit of ring-constrained analogues of buprenorphine, we wished to prepare 6-O-demethylated analogues of the thevinols and orvinols. Previously it had been disclosed that lithium aluminum hydride (LAH) in THF containing a chlorinated solvent could achieve this transformation. Here we report