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Hydride Transfer by Hydrido Transition-Metal Complexes. Ionic Hydrogenation of Aldehydes and Ketones, and Structural Characterization of an Alcohol Complex

✍ Scribed by Dr. Jeong-Sup Song; Dr. David J. Szalda; Dr. R. Morris Bullock; Dr. Christophe J. C. Lawrie; Dr. Mikhail A. Rodkin; Prof. Jack R. Norton

Publisher: John Wiley and Sons
Year: 1992
Tongue: English
Weight: 394 KB
Volume: 31
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.199212331

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## Abstract A dicationic dichloro‐bipyridine‐ruthenium complex shows very high catalytic activity in redox isomerization of allylic alcohols but a relatively low one in transfer hydrogenation of ketones; surprisingly, the analogous dimethyl‐bipyridine‐ruthenium complex shows reverse catalytic activ