Hydrazine carbodithioic acid pyridinium-2-yl methyl ester chloride
✍ Scribed by Crouse, Karen A. ;Chew, Kar Teng ;Yamin, Bohari M. ;Ng, Seik Weng ;Tarafder, M. T. H.
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 295 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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## Abstract 4‐(4,6‐Dimethylpyrimidin‐2‐yl)‐3‐thio‐allophanic acid methyl ester was synthesized with mixing 2‐amino‐4,6‐dimethylpyrimidine, potassium thiocyanate and methyl chloroformate in ethyl acetate. Single crystals suitable for X‐ray diffraction measurement were obtained by recrystallization f
## Abstract magnified image The title ester **1** reacted with hydrazine hydrate to give hydrazide **2**, which underwent intramolecular cyclization to yield 1‐amino‐7‐phenyl‐1__H__‐imidazo[1,2‐__a__]pyrimidine‐2,5‐dione (**3**) or took place in a substitution reaction with benzylamine to form __N