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Hydration of the CH Groups in 1,4-Dioxane Probed by NMR and IR: Contribution of Blue-Shifting CH···OH 2 Hydrogen Bonds

✍ Scribed by Mizuno, Kazuko; Imafuji, Shingo; Fujiwara, Teruko; Ohta, Tomoko; Tamiya, Yuka


Book ID
127360874
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
141 KB
Volume
107
Category
Article
ISSN
0022-3654

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CH···N and CH···O intramolecular hydroge
✍ Andrei V. Afonin; Igor A. Ushakov; Alexander V. Vashchenko; Dmitry E. Simonenko; 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 167 KB

## Abstract According to the ^1^H, ^13^C and ^15^N NMR spectroscopic data and DFT calculations, the __E__‐isomer of 1‐vinylpyrrole‐2‐carbaldehyde adopts preferable conformation with the __anti__‐orientation of the vinyl group relative to the carbaldehyde oxime group and with the __syn__‐arrangement