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Hydrates of (methane + cis-2-butene) and (methane + trans-2-butene)

✍ Scribed by G.D Holder; V.A Kamath

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
124 KB
Volume
16
Category
Article
ISSN
0021-9614

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📜 SIMILAR VOLUMES

H2S-promoted thermal isomerization of bu
H2S-promoted thermal isomerization of butene-2 CIS to butene-1 or butene-2 trans around 500°C
✍ C. Richard; A. Boiveaut; R. Martin 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 470 KB

H2S increases the thermal isomerization of butene-2 cis (B,) to butene-1 (B1) and butene-2 trans (Bt) around 500°C. This effect is interpreted on the basis of a free radical mechanism in which buten-2-yl and thiyl free radicals are the main chain carriers. B1 formation is essentially explained by th

Temperature dependence of the rate const
Temperature dependence of the rate constants of the reactions of oxygen atoms with trans-2-butene, cis-2-butene, 2-methylpropene, 2-methyl-2-butene, and 2,3-dimethyl-2-butene
✍ H. Biehl; J. Bittner; B. Bohn; R. Geers-Müller; F. Stuhl 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 559 KB

## Abstract The kinetics of the reactions of ground state oxygen atoms with __trans__‐2‐butene, __cis__‐2‐butene, 2‐methylpropene, 2‐methyl‐2‐butene, and 2,3‐dimethyl‐2‐butene was investigated in the temperature range 200 to 370K. In this range, the rate constants are (in units 10^−11^ cm^3^ s^−1^)

Thermal isomerization of cis- or trans-2
Thermal isomerization of cis- or trans-2-butene. The unimolecular elimination of hydrogen from cis-2-butene around 500°C
✍ D. Masson; C. Richard; R. Martin 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 300 KB

## Abstract An analytical and kinetic study of the thermal reaction of __cis__‐ or __trans__‐2‐butene has been performed in a static system over the temperature range of 480–550°C and at a low extent of reaction and initial pressures of 10–100 torr. The rate constant of the unimolecular __cis–tran

Abstraction by hydrogen atoms from ethyl
Abstraction by hydrogen atoms from ethylene, propylene, butene-1, and cis- and trans-butene-2
✍ W. E. Falconer; W. A. Sunder 📂 Article 📅 1972 🏛 John Wiley and Sons 🌐 English ⚖ 455 KB

The position of abstraction by H atoms from ethylene, propylene, butene-1, and cisand trans-butene-2 and the rates of abstraction relative to addition have been measured at 25°C. From ethylene, abstraction relative to addition was 5 3 X lo-\*. For propylene, butene-1, cis-butene-2, and trans-butene

Experimental and theoretical compton pro
Experimental and theoretical compton profiles of CIS and trans-2-butene
✍ R.S. Holt; M. Cooper; D.M. Hirst 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 511 KB

The Compton profdes of the geometrïc ïsomers cis and trans-2-butene (CaHa) have been measured in the gas phase using 59.54 keV =oamma rays. The measured profdes are compared with profdes derived from SCF end LM0 modeIs. NO significant differences between the measured profdes are observed. However, c