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Hydrated Alkali Metal Halides as Efficient Catalysts for the Synthesis of Cyclic Carbonates from CO2 and Epoxides

โœ Scribed by Xi ZHOU; Yi ZHANG; Xiangui YANG; Jie YAO; Gongying WANG


Publisher
Elsevier Science
Year
2010
Weight
255 KB
Volume
31
Category
Article
ISSN
1872-2067

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Intramolecularly two-centered cooperatio
โœ Xiang Zhang; Yin-Bao Jia; Xiao-Bing Lu; Bo Li; Hui Wang; Li-Cheng Sun ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 202 KB

A catalyst system containing an electrophilic center and a sterically hindered nucleophilic center in one molecule was applied to the cycloaddition reaction of CO 2 and epoxides. This intramolecularly two-centered cooperation catalyst showed activity even at a high [epoxide]/[catalyst] ratio up to 5