Hybridization effect on C-C bond length
β Scribed by Tomoo Miyazaki
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- French
- Weight
- 228 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
THE discovery that the C13-H nuclear spin-spin coupling constant appears to be a linear function of the amount of s-character in the carbon orbital from which a C-H bond is formed1 has made direct estimation of hybridization possible for the first time. In cyclopropanela and certain cyclopropenes2 t
Two-bond deuterium-induced isotope effects ('A) have been studied in several neutral x-systems (64dimethylfulvene, cyclohexene and cyclohexa-1,ldiene). Isotope effects on the 13C shifts of adjacent carbons are invariably to higher field, and vary from -84 to -139 ppb. In combination with literature